《分析化學(xué)》上冊(cè)
第一章 緒論
分析化學(xué):analytical chemistry
定性分析:qualitative analysis
定量分析:quantitative analysis
物理分析:physical analysis
物理化學(xué)分析:physico-chemical analysis
儀器分析法:instrumental analysis
流動(dòng)注射分析法:flow injection analysis;FIA
順序注射分析法:sequentical injection analysis;SIA
化學(xué)計(jì)量學(xué):chemometrics
第二章 誤差的分析數(shù)據(jù)處理
絕對(duì)誤差:absolute error
相對(duì)誤差:relative error
系統(tǒng)誤差:systematic error
可定誤差:determinate error
隨機(jī)誤差:accidental error
不可定誤差:indeterminate error
準(zhǔn)確度:accuracy
精確度:precision
偏差:debiation,d
平均偏差:average debiation
相對(duì)平均偏差:relative average debiation
標(biāo)準(zhǔn)偏差(標(biāo)準(zhǔn)差):standerd deviation;S
相對(duì)平均偏差:relatibe standard deviation;RSD
變異系數(shù):coefficient of variation
誤差傳遞:propagation of error
有效數(shù)字:significant figure
置信水平:confidence level
顯著性水平:level of significance
合并標(biāo)準(zhǔn)偏差(組合標(biāo)準(zhǔn)差):pooled standard debiation
舍棄商:rejection quotient ;Q
化學(xué)定量分析
第三章 滴定分析概論
滴定分析法:titrametric analysis
滴定:titration
容量分析法:volumetric analysis
化學(xué)計(jì)量點(diǎn):stoichiometric point
等當(dāng)點(diǎn):equivalent point
電荷平衡:charge balance
電荷平衡式:charge balance equation
質(zhì)量平衡:mass balance
物料平衡:material balance
質(zhì)量平衡式:mass balance equation
第四章 酸堿滴定法
酸堿滴定法:acid-base titrations
質(zhì)子自遞反應(yīng):autoprotolysis reaction
質(zhì)子自遞常數(shù):autoprotolysis constant
質(zhì)子條件式:proton balance equation
酸堿指示劑:acid-base indicator
指示劑常數(shù):indicator constant
變色范圍:colour change interval
混合指示劑:mixed indicator
雙指示劑滴定法:double indicator titration
第五章 非水滴定法
非水滴定法:nonaqueous titrations
質(zhì)子溶劑:protonic solvent
酸性溶劑:acid solvent
堿性溶劑:basic solvent
兩性溶劑:amphototeric solvent
無(wú)質(zhì)子溶劑:aprotic solvent
均化效應(yīng):differentiating effect
區(qū)分性溶劑:differentiating solvent
離子化:ionization
離解:dissociation
結(jié)晶紫:crystal violet
萘酚苯甲醇: α-naphthalphenol benzyl alcohol
奎哪啶紅:quinadinered
百里酚藍(lán):thymol blue
偶氮紫:azo violet
溴酚藍(lán):bromophenol blue
第六章 配位滴定法
配位滴定法:compleximetry
乙二胺四乙酸:ethylenediamine tetraacetic acid,EDTA
螯合物:chelate compound
金屬指示劑:metal lochrome indcator
第七章 氧化還原滴定法
氧化還原滴定法:oxidation-reduction titration
碘量法:iodimetry
溴量法:bromimetry ]
溴量法:bromine method
鈰量法:cerimetry
高錳酸鉀法:potassium permanganate method
條件電位:conditional potential
溴酸鉀法:potassium bromate method
硫酸鈰法:cerium sulphate method
偏高碘酸:metaperiodic acid
高碘酸鹽:periodate
亞硝酸鈉法:sodium nitrite method
重氮化反應(yīng):diazotization reaction#p#分頁(yè)標(biāo)題#e#
重氮化滴定法:diazotization titration
亞硝基化反應(yīng):nitrozation reaction
亞硝基化滴定法:nitrozation titration
外指示劑:external indicator
外指示劑:outside indicator
重鉻酸鉀法:potassium dichromate method
第八章 沉淀滴定法
沉淀滴定法:precipitation titration
容量滴定法:volumetric precipitation method
銀量法:argentometric method
第九章 重量分析法
重量分析法:gravimetric analysis
揮發(fā)法:volatilization method
引濕水(濕存水):water of hydroscopicity
包埋(藏)水:occluded water
吸入水:water of imbibition
結(jié)晶水:water of crystallization
組成水:water of composition
液-液萃取法:liquid-liquid extration
溶劑萃取法:solvent extration
反萃取:counter extraction
分配系數(shù):partition coefficient
分配比:distribution ratio
離子對(duì)(離子締合物):ion pair
沉淀形式:precipitation forms
稱量形式:weighing forms
《分析化學(xué)》下冊(cè)
儀器分析 概述
物理分析:physical analysis
物理化學(xué)分析:physicochemical analysis
儀器分析:instrumental analysis
第十章 電位法及永停滴定法
電化學(xué)分析:electrochemical analysis
電解法:electrolytic analysis method
電重量法:electtogravimetry
庫(kù)侖法:coulometry
庫(kù)侖滴定法:coulometric titration
電導(dǎo)法:conductometry
電導(dǎo)分析法:conductometric analysis
電導(dǎo)滴定法:conductometric titration
電位法:potentiometry
直接電位法:dirext potentiometry
電位滴定法:potentiometric titration
伏安法:voltammetry
極譜法:polarography
溶出法:stripping method
電流滴定法:amperometric titration
化學(xué)雙電層:chemical double layer
相界電位:phase boundary potential
金屬電極電位:electrode potential
化學(xué)電池:chemical cell
液接界面:liquid junction boundary
原電池:galvanic cell
電解池:electrolytic cell
負(fù)極:cathrode
正極:anode
電池電動(dòng)勢(shì):eletromotive force
指示電極:indicator electrode
參比電極:reference electroade
標(biāo)準(zhǔn)氫電極:standard hydrogen electrode
一級(jí)參比電極:primary reference electrode
飽和甘汞電極:standard calomel electrode
銀-氯化銀電極:silver silver-chloride electrode
液接界面:liquid junction boundary
不對(duì)稱電位:asymmetry potential
表觀PH值:apparent PH
復(fù)合PH電極:combination PH electrode
離子選擇電極:ion selective electrode
敏感器:sensor
晶體電極:crystalline electrodes
均相膜電極:homogeneous membrance electrodes
非均相膜電極:heterog eneous membrance electrodes
非晶體電極:non- crystalline electrodes
剛性基質(zhì)電極:rigid matrix electrode
流流體載動(dòng)電極:electrode with a mobile carrier
氣敏電極:gas sensing electrodes
酶電極:enzyme electrodes
金屬氧化物半導(dǎo)體場(chǎng)效應(yīng)晶體管:MOSFET
離子選擇場(chǎng)效應(yīng)管:ISFET
總離子強(qiáng)度調(diào)節(jié)緩沖劑:total ion strength adjustment buffer,TISAB
永停滴定法:dead-stop titration
雙電流滴定法(雙安培滴定法):double amperometric titration
第十一章 光譜分析法概論
普朗克常數(shù):Plank constant#p#分頁(yè)標(biāo)題#e#
電磁波譜:electromagnetic spectrum
光譜:spectrum
光譜分析法:spectroscopic analysis
原子發(fā)射光譜法:atomic emission spectroscopy
質(zhì)量譜:mass spectrum
質(zhì)譜法:mass spectroscopy,MS
第十二章 紫外-可見(jiàn)分光光度法
紫外-可見(jiàn)分光光度法:ultraviolet and visible spectrophotometry;UV-vis
肩峰:shoulder peak
末端吸收:end absorbtion
生色團(tuán):chromophore
助色團(tuán):auxochrome
紅移:red shift
長(zhǎng)移:bathochromic shift
短移:hypsochromic shift
藍(lán)(紫)移:blue shift
增色效應(yīng)(濃色效應(yīng)):hyperchromic effect
減色效應(yīng)(淡色效應(yīng)):hypochromic effect
強(qiáng)帶:strong band
弱帶:weak band
吸收帶:absorption band
透光率:transmitance,T
吸光度:absorbance
譜帶寬度:band width
雜散光:stray light
噪聲:noise
暗噪聲:dark noise
散粒噪聲:signal shot noise
閃耀光柵:blazed grating
全息光柵:holographic graaing
光二極管陣列檢測(cè)器:photodiode array detector
偏最小二乘法:partial least squares method ,PLS
褶合光譜法:convolution spectrometry
褶合變換:convolution transform,CT
離散小波變換:wavelet transform,WT
多尺度細(xì)化分析:multiscale analysis
供電子取代基:electron donating group
吸電子取代基:electron with-drawing group
第十三章 熒光分析法
熒光:fluorescence
熒光分析法:fluorometry
X-射線熒光分析法:X-ray fulorometry
原子熒光分析法:atomic fluorometry
分子熒光分析法:molecular fluorometry
振動(dòng)弛豫:vibrational relexation
內(nèi)轉(zhuǎn)換:internal conversion
外轉(zhuǎn)換:external conversion
體系間跨越:intersystem crossing
激發(fā)光譜:excitation spectrum
熒光光譜:fluorescence spectrum
斯托克斯位移:Stokes shift
熒光壽命:fluorescence life time
熒光效率:fluorescence efficiency
熒光量子產(chǎn)率:fluorescence quantum yield
熒光熄滅法:fluorescence quemching method
散射光:scattering light
瑞利光:Reyleith scanttering light
拉曼光:Raman scattering light
第十四章 紅外分光光度法
紅外線:infrared ray,IR
中紅外吸收光譜:mid-infrared absorption spectrum,Mid-IR
遠(yuǎn)紅外光譜:Far-IR
微波譜:microwave spectrum,MV
紅外吸收光譜法:infrared spectroscopy
紅外分光光度法:infrared spectrophotometry
振動(dòng)形式:mode of vibration
伸縮振動(dòng):stretching vibration
對(duì)稱伸縮振動(dòng):symmetrical stretching vibration
不對(duì)稱伸縮振動(dòng):asymmetrical stretching vibration
彎曲振動(dòng):bending vibration
變形振動(dòng):formation vibration
面內(nèi)彎曲振動(dòng):in-plane bending vibration,β
剪式振動(dòng):scissoring vibration,δ
面內(nèi)搖擺振動(dòng):rocking vibration,ρ
面外彎曲振動(dòng):out-of-plane bending vibration,γ
面外搖擺振動(dòng):wagging vibration,ω
蜷曲振動(dòng):twisting vibration ,τ
對(duì)稱變形振動(dòng):symmetrical deformation vibration ,δs
不對(duì)稱變形振動(dòng):asymmetrical deformation vibration, δas
特征吸收峰:charateristic avsorption band
特征頻率:characteristic frequency
相關(guān)吸收峰:correlation absorption band#p#分頁(yè)標(biāo)題#e#
雜化影響:hybridization affect
環(huán)大小效應(yīng):ring size effect
吸收峰的強(qiáng)度:intensity of absorption band
環(huán)折疊振動(dòng):ring prckering vibration
第十五章 原子吸收分光光度法
原子光譜法:atomic spectroscopy
原子吸收分光光度法:atomic absorption spectrophotometry,AAS
原子發(fā)射分光光度法:atomic emmsion spectrophotometry,AES
原子熒光分光光度法:atomic fluorescence spectrophotometry,AFS
第十六章 核磁共振波譜法
核磁共振:nuclear magnetic resonance,NMR
核磁共振波譜:NMR spectrum
核磁共振波譜法:NMR spectroscopy
掃場(chǎng):swept field
掃頻:seept frequency
連續(xù)波核磁共振:continuous wave NMR,CW NMR
Fourier變換NMR:PFT-NMR,FT-NMR
二維核磁共振譜:2D-NMR
質(zhì)子核磁共振譜:proton magnetic resonance spectrum,PMR
氫譜:1H-NMR
碳-13核磁共振譜:13C-NMR spectrum,13CNMR
自旋角動(dòng)量:spin angular momentum
磁旋比:magnetogyric ratio
磁量子數(shù):magnetic quantum number,m
進(jìn)動(dòng):precession
弛豫歷程:relaxation mechanism
局部抗磁屏蔽:local diamagnetic shielding
屏蔽常數(shù):shielding constant
化學(xué)位移:chemical shift
國(guó)際純粹與應(yīng)用化學(xué)協(xié)會(huì):IUPAC
磁各向異性:magnetic anisotropy
遠(yuǎn)程屏蔽效應(yīng):long range shielding effect
結(jié)面:nodal plane
自旋-自旋偶合:spin-spin coupling
自旋-自旋分裂:spin=spin splitting
單峰:singlet,s
雙峰:doublet,d
三重峰:triplet,t
四重峰:quartet
五重峰:quintet
六重峰:sextet
偕偶:geminal coupling
鄰偶:vicinal coupling
遠(yuǎn)程偶合:long range coupling
磁等價(jià):magnetic eqivalence
自旋系統(tǒng):spin system
一級(jí)光譜:first order spectrum
二級(jí)光譜(二級(jí)圖譜):second order spectrum
C-H光譜:C-H correlated spectroscopy,C-H COSY
第十七章 質(zhì)譜法
質(zhì)譜分析法:mass spectrometry
質(zhì)譜:mass spectrum,MS
棒圖:bar graph
選擇離子檢測(cè):selected ion monitoring ,SIM
直接進(jìn)樣:direct probe inlet ,DPI
接口:interface
氣相色譜-質(zhì)譜聯(lián)用:gas chromatography-mass spectrometry,GC-MS
高效液相色譜-質(zhì)譜聯(lián)用:high performance liquid chromatography-mass spectrometry,HPLC-MS
電子轟擊離子源:electron impact source,EI
離子峰:quasi-molecular ions
化學(xué)離子源:chemical ionization source,CI
場(chǎng)電離:field ionization,FI
場(chǎng)解析:field desorptiion,FD
快速原子轟擊離子源:fast stom bombardment ,FAB
質(zhì)量分析器:mass analyzer
磁質(zhì)譜儀:magnetic-sector mass spectrometer
四極桿質(zhì)譜儀(四極質(zhì)譜儀):quadrupole mass spectrometer
原子質(zhì)量單位:amu
離子豐度:ion abundance
相對(duì)豐度(相對(duì)強(qiáng)度):relative avundance
基峰:base peak
質(zhì)量范圍:mass range
分辨率:resolution
靈敏度:sensitivity
信噪比:S/N
分子離子:molecular ion
碎片離子:fragment ion
同位素離子:isotopic ion
亞穩(wěn)離子:metastable ion
亞穩(wěn)峰:metastable peak
母離子:paren ion
子離子:daughter
含奇數(shù)個(gè)電子的離子:odd electron
含偶數(shù)個(gè)電子的離子:even eletron,EE
均裂:homolytic cleavage
異裂(非均裂):heterolytic cleavage#p#分頁(yè)標(biāo)題#e#
半均裂:hemi-homolysis cleavage
重排:rearragement
分子量:MW
α-裂解:α-cleavage
第十八章 色譜分析法概論
色譜法(層析法):chromatography
固定相:stationary phase
流動(dòng)相:mobile phase
超臨界流體色譜法:SFC
高效毛細(xì)管電泳法:high performance capillary electroporesis,HPEC
氣相色譜法:gas chromatography,GC
液相色譜法:liquid cromatography,LC
超臨界流體色譜法:supercritical fluid chromatography,SFC
氣-固色譜法:GSC
氣-液色譜法:GLC
液-固色譜法:LSC
液-液色譜法:LLC
柱色譜法:column chromatography
填充柱:packed column
毛細(xì)管柱:capillary column
微填充柱:icrobore packed column
高效液相色譜法:high performance liquid chromatography,HPLC
平板色譜法:planar
平板色譜法:plane chromatography
紙色譜法:paper chromatography
薄層色譜法:thin layer chromatography,TLC
薄膜色譜法;thiin film chomatography
毛細(xì)管電泳法:capillary electrophoresis,CE
分配色譜法:partition chromatography
吸附色譜法:adsorpion chromaography
離子交換色譜法:ion exchange chromatography,IEC
空間排阻色譜法:steric exclusion chromatography,SEC
親和色譜法:affinity chromatography
分配系數(shù):distribution cofficient
狹義分配系數(shù):partition coefficient
凝膠色譜法:gel chromatography
凝膠滲透色譜法:gel permeation chromatography,GPC
凝膠過(guò)濾色譜法:gel filtration chromatography,GFC
滲透系數(shù):permeation coefficien;Kp
化學(xué)鍵合相色譜法:chemically bonded-phase chromatography
分配系數(shù):distribution coefficient
靛菁綠:indocyanine
氣相色譜-傅立葉變換紅外光譜:GC-FTIR
第十九章 經(jīng)典液相色譜法
薄層色譜法:TLC
吸附:adsorption
活化:activation
脫活性:deactivation
交聯(lián)度:degree of cross linking
交換容量:exchange capacity
薄層板:thin layer plate
展開(kāi)劑:developing solvent ,developer
臨界膠束濃度:criticak micolle concentration ,CMC
相對(duì)比移值:relative Rf, Rr
分離度:resolution ,R
分離數(shù):separation number,SN
煅石膏:Gypsum
羧甲基纖維素鈉:CMC-Na
吸收光譜聯(lián)用:TLC-UV
薄層色譜-熒光聯(lián)用:TLC-F
薄層色譜-紅外吸收光譜聯(lián)用:TLC-IR
薄層色譜法:TLC-MS
紙色譜法:paper chromatography
上行展開(kāi):ascending development
下行法展開(kāi):descending development
雙向展開(kāi):two dimensional develoooment
第二十章 氣相色譜法
氣相色譜法:gas chromatography
前延峰:leading peak
拖尾峰:tailing peak
對(duì)稱因子:symmetry factor,fs
保留時(shí)間:retention time
保留體積:retention volume
死時(shí)間:dead time
調(diào)整保留時(shí)間:asjusted retention time
半峰寬:peak width at half height,W1/2 or Y1/2
峰寬:peak width,W
等溫線:isotherm
理論塔板高度:height equivalent to atheoretical plate
化學(xué)鍵合相:chemically bonded phase
丁二酸二乙二醇聚酯:polydiethylene glycol succinate,PDEGS,DEGS
高分子多孔微球:GDX
苯乙烯:STY
乙基乙烯苯:EST
二乙烯苯:DVB
涂壁毛細(xì)管柱:wall coated open tubular column,WCOT#p#分頁(yè)標(biāo)題#e#
載體涂層毛細(xì)管柱:supprot coated open tubular column,SCOT
熱導(dǎo)檢測(cè)器:thermal conductivity detector,TCD
氫焰離子化檢測(cè)器:hydrogen flame ionization detector,FID
電子捕獲檢測(cè)器:electron capture detector ,ECD
噪聲:noise,N
漂移:drift,d
靈敏度:sensitivity
檢測(cè)限(敏感度):detectability,D,M
分離度:resolution
歸一化法:normalization method
外標(biāo)法:external standardization
第二十一章 高效液相色譜法
高效液相色譜法:high performance liquid chromatography,HPLC
高速液相色譜法:high speed LC,HSLC
高壓液相色譜法:high pressure LC,HPLC
高分辨液相色譜法:high resolution LC,HRLC
液固吸附色譜法(液固色譜法):liquid-solid adsorption chromatography,LSC
液液色譜法:liquid-liquid chromatography,LLC
正相:normal phase,NP
反相:reversed phase,RP
化學(xué)鍵合相色譜法:bonded phase chromatography,BPC
十八烷基:octadecylselyl,ODS
離子對(duì)色譜法:paired ion chromatography,PIC
反相離子對(duì)色譜法:RPIC
離子抑制色譜法:ion suppression chromatography,ISC
離子色譜法:ion chromatography,IC
手性色譜法:chiral chromatography,CC
環(huán)糊精色譜法:cyclodextrin chromatography,CDC
膠束色譜法:micellar chromatography,MC
親和色譜法:affinity chromatography,AC
固定相:stationary phase
化學(xué)鍵合相:chemically bonde phase
封尾、封頂、遮蓋:end capping
手性固定相:chiral stationary phase,CSP
恒組成溶劑洗脫:isocraic elution
梯度洗脫:gradient elution
紫外檢測(cè)器:ultraviolet detector,UVD
熒光檢測(cè)器:fluorophotomeric detector,FD
電化學(xué)檢測(cè)器:ECD
示差折光檢測(cè)器:RID
光電二極管檢測(cè)器:photodiode array detector ,DAD
三維光譜-波譜圖:3D-spectrochromatogram
蒸發(fā)光散射檢測(cè)器:evaporative light scattering detector,ELSD
安培檢測(cè)器:ampere detector,AD
高效毛細(xì)管電泳法:high performance capillary electrophoresis,HPCE
淌度:mobility
電泳:electrophoresis
電滲:electroosmosis
動(dòng)力進(jìn)樣:hydrodynamic injection
電動(dòng)進(jìn)樣:electrokinetic injection
毛細(xì)管區(qū)帶電泳法:capillary zone electrophoresis,CZE
膠束電動(dòng)毛細(xì)管色譜:micellar electrokinetic capillary chromatography,MECC
毛細(xì)管凝膠電泳:capillary gel electrophoresis,CGE
篩分:sieving